That's not you PCV that you have that breather on, but its OK to vent that to atmosphere like you have.
If you are looking at your photo, the PCV is visible just to the right of the header. You can see the ring around the base of it. Its a 90* plastic bit with a line that will run towards the back of the motor, under the coil pack. There will be rubber hose coming off the PCV then it will attach to a solid tube under the coil pack, then another rubber hose from there to the manifold IIRC.
You will want to put the catch can inline between the PCV and the manifold.
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